Sailor Moon S Movie
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From the sky, Kakeru (an astronomer) sees something odd falling from the sky. When it lands near his observatory, he finds an odd looking crystal, and he brings it back home with him. But as fate would have it, he also ends up saving Luna from almost certain death.
The Crystal was actually part of the Ice Queens weapon meant to freeze the Earth so she could add it to her collection. The Crystal links itself to Kakeru and he becomes very sick. Luna ends up falling in love with Kakeru. Kakeru ends up breaking a relationship with Himeko.
The Crystal is eventually found by the Ice Queen. She starts to freeze Earth. Luna determines that it was the crystal causing all the problems and figures that if she were human she could help Kakeru. The Senshi team up together to fight the Ice Queen. They use all their power and the Silver Crystal to destroy the Queen and grant Luna's wish.