NOTE: k = Boltzmann constant = 1.38E-23 NOTE: R = the gas constant = 8.314 NOTE: remember to use Celcius and Kelvin when appropriate
1.1: Molecular Speeds a) (.004 kg)/(1 mol) * (1 mol)/(6.022e23 atoms) b) "The total kinetic energy of the collection of X atoms is KE." <KE>Ar = KE/X <KE>He = KE/X c) m = (atomic weight)/(6.022e23 atoms) <KE> = (1/2)*m*v2 d) KE = (3/2)kT T = [<KE>*(3/2)]/k
1.2: Mass On Spring a) <PE> = 1/2*k*T (k = 1.38*10^-23) b) <v> = 0 c) PE + KE = kT <PE> + (1/2)mv2 = kT <v2> = [2*(kT-<PE>)]/m d) 1
1.3: Equipartition of Energy a) N = pV / kT **NOTE: convert liters to m3 U = (5/2)*N*k*T b) find weight of N2: (.028kg)/(1mol) * (1mol)/(6.022e23 atoms) (3/2)kT = (1/2)mv2 c) n = (weight) * (1mol)/(63g) U = 3nRT d) U = mgh :: h = U/(mg) U = (1/2)mv2 :: vcm = sqrt[2U/m]
1.4: Gas Laws a) N/V = p/(k*T) b) Temperature remains the same c) p1V1 = p2V2 d) N = N/V * Vi W=NkT*ln(Vf/Vi)
1.5: First Law of Thermodynamics a) V1/T1 = V2/T2 b) N = pV / kT delta.U = (5/2)*N*k*(Tf - Ti) c) Wby = p(Vf - Vi) d) delta.U = Q - Wby Q = delta.U + Wby